Junri Zhao, Golam Sarwar, Brett Gantt, Kristen Foley, Barron H. Henderson, Havala O. T. Pye, Kathleen M. Fahey, Daiwen Kang, Rohit Mathur, Yan Zhang, Qinyi Li, Alfonso Saiz-Lopez
Atmospheric Environment, Volume 244,117961, https://doi.org/10.1016/j.atmosenv.2020.117961, 2021
Abstract:
We implement oceanic dimethylsulfide (DMS) emissions and its atmospheric chemical reactions into the Community Multiscale Air Quality (CMAQv53) model and perform annual simulations without and with DMS chemistry to quantify its impact on tropospheric composition and air quality over the Northern Hemisphere. DMS chemistry enhances both sulfur dioxide (SO2) and sulfate (SO42−) over seawater and coastal areas. It enhances annual mean surface SO2 concentration by +46 pptv and SO42−by +0.33 μg/m3 and decreases aerosol nitrate concentration by −0.07 μg/m3 over seawater compared to the simulation without DMS chemistry. The changes decrease with altitude and are limited to the lower atmosphere. Impacts of DMS chemistry on SO42− are largest in the summer and lowest in the fall due to the seasonality of DMS emissions, atmospheric photochemistry and resultant oxidant levels. Hydroxyl and nitrate radical-initiated pathways oxidize 75% of the DMS while halogen-initiated pathways oxidize 25%. DMS chemistry leads to more acidic particles over seawater by decreasing aerosol pH. Increased SO42−from DMS enhances atmospheric extinction while lower aerosol nitrate reduces the extinction so that the net effect of DMS chemistry on visibility tends to remain unchanged over most of the seawater.